Zhang Pei, Zhang Shufen, Han Gang
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, China.
Molecules. 2009 Sep 18;14(9):3688-93. doi: 10.3390/molecules14093688.
A novel asymmetric zinc (II) phthalocyanine substituted by one lipophilic octadecyloxyl group and three hydrophilic glucosyl groups was synthesized. Using Q-TOF MS, the major byproducts formed during the deprotection processes were identified. An improved procedure was worked out to convert these byproducts to the desired product in quantitative yield.
合成了一种新型的不对称锌（II）酞菁，其被一个亲脂性的十八烷氧基和三个亲水性的葡萄糖基取代。使用Q-TOF质谱仪鉴定了脱保护过程中形成的主要副产物。制定了一种改进的方法，以定量产率将这些副产物转化为所需产物。
