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来自哥伦比亚的罗勒属植物Ocimum gratissimum L.和Ocimum campechianum Mill.精油的丁香酚和甲基丁香酚化学型。

Eugenol and methyl eugenol chemotypes of essential oil of species Ocimum gratissimum L. and Ocimum campechianum Mill. from Colombia.

作者信息

Pino Benitez Nayive, Meléndez León Erika M, Stashenko Elena E

机构信息

Universidad Tecnológica del Chocó, bloque 6 laboratorio 316, Grupo de Productos Naturales, Quibdó-Chocó, Colombia.

出版信息

J Chromatogr Sci. 2009 Oct;47(9):800-3. doi: 10.1093/chromsci/47.9.800.

Abstract

Essential oils chemical constituents of leaves of O. gratissimum and O. campechianum of the Lamiaceae family, collected in Chocó of northwest Colombian, were obtained by microwave-assisted hydrodistillation and analyzed by gas chromatography coupled with mass spectrometry. A total of 33 and 37 compounds were identified in the essential oil of O. gratissimum and O. campechianum, respectively. O. gratissimum's main essential oils were eugenol (43.2%), 1,8-cineole (12.8%) and beta-selinene (9.0%); in the O. campechianum essential oil, the main components were methyl eugenol (12.0%), germacrene D (10.1%), and eugenol (9.0%). Main distribution of compounds in these essential oils are 25.0% monoterpenes hydrocarbons, 15.0% monoterpenes oxygenated, 35.0% sesquiterpenes hydrocarbons, 7.5% other oxygenated components for O. gratissimum, 33.9% sesquiterpenes hydrocarbons, and 10.7% their respective oxygenated derivates; for O. campechianum, the distribution was 10.7% monoterpenes hydrocarbons and 7.1% their respective oxygenated derivates and 3.6% phenylpropanes. According to the essential oils chemical composition of Ocimum gratissimum and O. campechianum, they are classified as eugenol and methyl eugenol chemotype, respectively.

摘要

对采集于哥伦比亚西北部乔科省的唇形科牛至属植物牛至(Origanum gratissimum)和墨西哥牛至(Origanum campechianum)叶片的精油化学成分,采用微波辅助水蒸馏法提取,并通过气相色谱-质谱联用仪进行分析。牛至和墨西哥牛至精油中分别鉴定出33种和37种化合物。牛至精油的主要成分是丁香酚(43.2%)、1,8-桉叶素(12.8%)和β-芹子烯(9.0%);墨西哥牛至精油的主要成分是甲基丁香酚(12.0%)、吉马烯D(10.1%)和丁香酚(9.0%)。这些精油中化合物的主要分布情况为:牛至中,单萜烃类占25.0%,单萜氧化合物占15.0%,倍半萜烃类占35.0%,其他氧化成分占7.5%;墨西哥牛至中,倍半萜烃类占33.9%,其相应的氧化衍生物占10.7%,单萜烃类占10.7%,其相应的氧化衍生物占7.1%,苯丙烷类占3.6%。根据牛至和墨西哥牛至的精油化学成分,它们分别被归类为丁香酚化学型和甲基丁香酚化学型。

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