Pino Benitez Nayive, Meléndez León Erika M, Stashenko Elena E
Universidad Tecnológica del Chocó, bloque 6 laboratorio 316, Grupo de Productos Naturales, Quibdó-Chocó, Colombia.
J Chromatogr Sci. 2009 Oct;47(9):800-3. doi: 10.1093/chromsci/47.9.800.
Essential oils chemical constituents of leaves of O. gratissimum and O. campechianum of the Lamiaceae family, collected in Chocó of northwest Colombian, were obtained by microwave-assisted hydrodistillation and analyzed by gas chromatography coupled with mass spectrometry. A total of 33 and 37 compounds were identified in the essential oil of O. gratissimum and O. campechianum, respectively. O. gratissimum's main essential oils were eugenol (43.2%), 1,8-cineole (12.8%) and beta-selinene (9.0%); in the O. campechianum essential oil, the main components were methyl eugenol (12.0%), germacrene D (10.1%), and eugenol (9.0%). Main distribution of compounds in these essential oils are 25.0% monoterpenes hydrocarbons, 15.0% monoterpenes oxygenated, 35.0% sesquiterpenes hydrocarbons, 7.5% other oxygenated components for O. gratissimum, 33.9% sesquiterpenes hydrocarbons, and 10.7% their respective oxygenated derivates; for O. campechianum, the distribution was 10.7% monoterpenes hydrocarbons and 7.1% their respective oxygenated derivates and 3.6% phenylpropanes. According to the essential oils chemical composition of Ocimum gratissimum and O. campechianum, they are classified as eugenol and methyl eugenol chemotype, respectively.
对采集于哥伦比亚西北部乔科省的唇形科牛至属植物牛至(Origanum gratissimum)和墨西哥牛至(Origanum campechianum)叶片的精油化学成分,采用微波辅助水蒸馏法提取,并通过气相色谱-质谱联用仪进行分析。牛至和墨西哥牛至精油中分别鉴定出33种和37种化合物。牛至精油的主要成分是丁香酚(43.2%)、1,8-桉叶素(12.8%)和β-芹子烯(9.0%);墨西哥牛至精油的主要成分是甲基丁香酚(12.0%)、吉马烯D(10.1%)和丁香酚(9.0%)。这些精油中化合物的主要分布情况为:牛至中,单萜烃类占25.0%,单萜氧化合物占15.0%,倍半萜烃类占35.0%,其他氧化成分占7.5%;墨西哥牛至中,倍半萜烃类占33.9%,其相应的氧化衍生物占10.7%,单萜烃类占10.7%,其相应的氧化衍生物占7.1%,苯丙烷类占3.6%。根据牛至和墨西哥牛至的精油化学成分,它们分别被归类为丁香酚化学型和甲基丁香酚化学型。