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从一种半翅目昆虫中确定一种新的保幼激素结构。

Structure determination of a new juvenile hormone from a heteropteran insect.

机构信息

National Institute of Agrobiological Sciences, Tsukuba, Ibaraki 305-8634, Japan.

出版信息

Org Lett. 2009 Nov 19;11(22):5234-7. doi: 10.1021/ol902161x.

DOI:10.1021/ol902161x
PMID:19863071
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2776382/
Abstract

The structure of the juvenile hormone (JH) in the suborder Heteroptera, order Hemiptera, has been known for a very long time to be different from the JH of other orders, but the structure has been a matter of controversy. The structure was first elucidated by an unprecedented approach involving the screening of a JH molecular library. The novel Heteroptera-specific JH (JHSB(3)) is a new category of JH that is featured by the skipped bisepoxide structure.

摘要

半翅目昆虫(即同翅目昆虫)的保幼激素(JH)结构很久以前就已被确认与其他目昆虫的 JH 结构不同,但该结构一直存在争议。其结构最初是通过前所未有的方法阐明的,该方法涉及 JH 分子文库的筛选。新型半翅目特异性 JH(JHSB(3))是 JH 的一个新类别,其特征是缺少双环氧化物结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/848e/2776382/23281a2f6c37/ol-2009-02161x_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/848e/2776382/8056f1850e46/ol-2009-02161x_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/848e/2776382/1bf833660a90/ol-2009-02161x_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/848e/2776382/fdb15f86b04c/ol-2009-02161x_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/848e/2776382/30bfa3895bc7/ol-2009-02161x_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/848e/2776382/23281a2f6c37/ol-2009-02161x_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/848e/2776382/8056f1850e46/ol-2009-02161x_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/848e/2776382/1bf833660a90/ol-2009-02161x_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/848e/2776382/fdb15f86b04c/ol-2009-02161x_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/848e/2776382/30bfa3895bc7/ol-2009-02161x_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/848e/2776382/23281a2f6c37/ol-2009-02161x_0003.jpg

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