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在离子模型基底上室温下形成的水单分子层上的稳定液态水滴。

Stable liquid water droplet on a water monolayer formed at room temperature on ionic model substrates.

作者信息

Wang Chunlei, Lu Hangjun, Wang Zhigang, Xiu Peng, Zhou Bo, Zuo Guanghong, Wan Rongzheng, Hu Jun, Fang Haiping

机构信息

Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai, 201800, China.

出版信息

Phys Rev Lett. 2009 Sep 25;103(13):137801. doi: 10.1103/PhysRevLett.103.137801.

DOI:10.1103/PhysRevLett.103.137801
PMID:19905541
Abstract

Using molecular dynamics simulation, we show direct evidence of the unexpected phenomenon of "water that does not wet a water monolayer" at room temperature. This phenomenon is attributed to the structure of the water beneath the water droplet, which exhibits an ordered water monolayer. Remarkably, there remains a considerable number of dangling OH bonds in this room temperature water monolayer, in contrast with the absence of dangling OH bonds at cryogenic temperature.

摘要

通过分子动力学模拟,我们展示了在室温下“水不润湿水单层”这一意外现象的直接证据。这种现象归因于水滴下方水的结构,其呈现出有序的水单层。值得注意的是,与低温下不存在悬空OH键相比,在这个室温下水单层中仍存在相当数量的悬空OH键。

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