铃木-宫浦偶联反应在芳基氨基甲酸酯、碳酸酯和磺酸盐中的应用。
Suzuki-Miyaura coupling of aryl carbamates, carbonates, and sulfamates.
机构信息
Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095, USA.
出版信息
J Am Chem Soc. 2009 Dec 16;131(49):17748-9. doi: 10.1021/ja906477r.
Abstract
The first Suzuki-Miyaura cross-couplings of carbamates, carbonates, and sulfamates is described. The method provides a powerful means of using simple derivatives of phenol as precursors to polysubstituted aromatic compounds, as exemplified by a concise synthesis of the anti-inflammatory drug flurbiprofen.
摘要
首次报道了碳酸酯、氨基甲酸酯和磺酸盐的铃木-宫浦交叉偶联反应。该方法为使用简单酚衍生物作为多取代芳族化合物的前体提供了有力手段，如抗炎药物氟比洛芬的简洁合成。
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