钯催化的 O-甲基肟与芳基硼酸的 C-H 官能化反应。
Pd-catalyzed C-H functionalizations of O-methyl oximes with arylboronic acids.
机构信息
Beijing National Laboratory of Molecular Sciences, College of Chemistry, Peking University, Beijing 100871, China.
出版信息
Org Lett. 2010 Jan 1;12(1):184-7. doi: 10.1021/ol902552v.
PMID:19954173
Abstract
Useful methods have been developed to construct ortho-arylated aryl aldoximes, aryl ketoximes, and fluorenones via Pd(II)-catalyzed direct C-H arylation by using arylboronic acids as arylating reagents based on the analysis of the pathways of direct functionalization of aryl aldoximes.
摘要
通过对芳基醛肟的直接官能化途径的分析，已经开发出了一些有用的方法，通过 Pd(II)催化的直接 C-H 芳基化反应，使用芳基硼酸作为芳基化试剂，来构建邻芳基化的芳基醛肟、芳基酮肟和芴酮。
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