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Gold(I)-catalyzed enantioselective synthesis of pyrazolidines, isoxazolidines, and tetrahydrooxazines.

作者信息

Lalonde R L, Wang Z J, Mba M, Lackner A D, Toste F Dean

机构信息

Department of Chemistry, University of California, Berkeley, CA 94720, USA.

出版信息

Angew Chem Int Ed Engl. 2010;49(3):598-601. doi: 10.1002/anie.200905000.

Abstract
摘要

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A powerful chiral counteranion motif for asymmetric catalysis.
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Asymmetric synthesis of medium-sized rings by intramolecular Au(I)-catalyzed cyclopropanation.
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Asymmetric gold-catalyzed hydroarylation/cyclization reactions.
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