Leibniz Institute for Polymer Research Dresden, Hohe Strasse 6, Dresden D-01069, Germany.
J Chem Phys. 2009 Dec 21;131(23):234907. doi: 10.1063/1.3273416.
By developing and making use of the potential theory of the polymer-mediated interaction between spherical colloids, we investigate the many-body effects on the depletion interaction among these colloids in the colloid-polymer mixture. As our main results, we obtain analytic expressions for the polymer end density in the presence of the colloids and the many-body depletion potential acting between these colloids in the "protein" limit. We present a comparison of our theoretical findings with the results of recent computer simulations.
通过开发和利用聚合物介导的球形胶体相互作用的势理论,我们研究了胶体-聚合物混合物中这些胶体之间的消耗相互作用的多体效应。作为我们的主要结果,我们获得了在胶体存在下聚合物末端密度和这些胶体之间的多体消耗势的解析表达式,在“蛋白质”极限下。我们将我们的理论结果与最近的计算机模拟结果进行了比较。