Palladium-catalyzed ligand-directed C-H functionalization reactions.
作者信息
Lyons Thomas W, Sanford Melanie S
机构信息
Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, USA.
出版信息
Chem Rev. 2010 Feb 10;110(2):1147-69. doi: 10.1021/cr900184e.
Abstract
摘要
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本文引用的文献
1
Transition Metal Catalyzed Coupling Reactions under C-H Activation.碳氢键活化下的过渡金属催化偶联反应
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2
Bimetallic Pd(III) complexes in palladium-catalysed carbon–heteroatom bond formation.钯催化碳-杂原子键形成中的双金属 Pd(III) 配合物。
Nat Chem. 2009 Jul;1(4):302-9. doi: 10.1038/nchem.246.
3
Organopalladium and platinum chemistry in oxidising milieu as models for organic synthesis involving the higher oxidation states of palladium.在氧化环境中有机钯和铂化学作为涉及钯的更高氧化态的有机合成模型。
Dalton Trans. 2009 Dec 21(47):10409-17. doi: 10.1039/b914080h. Epub 2009 Aug 28.
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Mechanistic comparison between Pd-catalyzed ligand-directed C-H chlorination and C-H acetoxylation.钯催化的配体导向C-H氯化反应与C-H乙酰氧基化反应之间的机理比较
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Palladium-catalyzed aromatic C-H halogenation with hydrogen halides by means of electrochemical oxidation.通过电化学氧化实现钯催化的芳烃C-H与卤化氢的卤化反应。
J Am Chem Soc. 2009 Aug 19;131(32):11310-1. doi: 10.1021/ja9049228.
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Palladium(II)-catalyzed regioselective direct C2 alkenylation of indoles and pyrroles assisted by the N-(2-pyridyl)sulfonyl protecting group.钯（II）催化的吲哚和吡咯的区域选择性直接C2烯基化反应，由N-（2-吡啶基）磺酰基保护基辅助。
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Recent advances in aryl-aryl bond formation by direct arylation.通过直接芳基化形成芳基-芳基键的最新进展。
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Synthetic and mechanistic studies of Pd-catalyzed C-H arylation with diaryliodonium salts: evidence for a bimetallic high oxidation state Pd intermediate.钯催化的与二芳基碘鎓盐的C-H芳基化反应的合成及机理研究：双金属高氧化态钯中间体的证据
J Am Chem Soc. 2009 Aug 12;131(31):11234-41. doi: 10.1021/ja904116k.
9
Pd(II)-catalyzed amination of C-H bonds using single-electron or two-electron oxidants.钯（II）催化的碳氢键胺化反应，使用单电子或双电子氧化剂。
J Am Chem Soc. 2009 Aug 12;131(31):10806-7. doi: 10.1021/ja904709b.
10
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