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硼氧烷化学及其应用:展望。

Boroxine chemistry and applications: A perspective.

机构信息

University of San Diego, 5998 Alcala Park, San Diego, CA 92110, USA.

出版信息

Dalton Trans. 2010 Feb 14;39(6):1423-31. doi: 10.1039/b917043j. Epub 2009 Nov 5.

DOI:10.1039/b917043j
PMID:20104295
Abstract

This perspective summarizes the chemistry of boroxines and outlines progress towards incorporating these ring structures into functional materials and macromolecular architectures. Special attention is paid to the dynamic covalent chemistry of boroxine ring construction and how these processes lead to novel molecular architectures and functional materials. Also highlighted in this perspective is the rich chemistry surrounding boroxine-ligand interactions and how these interactions flavor many areas of boroxine chemistry.

摘要

本观点总结了硼氧六环的化学性质,并概述了将这些环结构纳入功能材料和高分子结构的进展。特别关注硼氧六环构建的动态共价化学以及这些过程如何导致新的分子结构和功能材料。本观点还强调了硼氧六环-配体相互作用的丰富化学性质以及这些相互作用如何影响硼氧六环化学的许多领域。

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