Rh(I)催化的 1-烯基、1-炔基和 1-烯丙基-乙烯基环丙烷的分子内[3+2]环加成反应。
Rh(I)-catalyzed intramolecular [3 + 2] cycloaddition reactions of 1-ene-, 1-yne- and 1-allene-vinylcyclopropanes.
机构信息
Beijing National Laboratory of Molecular Sciences, College of Chemistry, Peking University, Beijing, 100871, China.
出版信息
Chem Commun (Camb). 2010 Feb 21;46(7):1059-61. doi: 10.1039/b922417c. Epub 2009 Dec 14.
DOI:10.1039/b922417c
PMID:20126712
Abstract
New Rh(I)-catalyzed intramolecular [3 + 2] cycloaddition reactions of 1-ene-, 1-yne and 1-allene-vinylcyclopropanes have been developed, affording an efficient and versatile synthesis of cyclopentane- and cyclopentene-embedded bicyclic structures.
摘要
新型 Rh(I) 催化的 1-烯、1-炔和 1-烯-乙烯基环丙烷的分子内 [3 + 2] 环加成反应已经被开发出来，为环戊烷和环戊烯嵌入式双环结构的高效和通用合成提供了一种方法。
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