Beijing National Laboratory of Molecular Sciences (BNLMS), College of Chemistry, Peking University, Beijing 100871, China.
Org Lett. 2012 Feb 3;14(3):692-5. doi: 10.1021/ol2031526. Epub 2012 Jan 18.
A cationic Rh(I)-catalyzed [5 + 1] cycloaddition of vinylcyclopropanes and CO has been developed, affording either β,γ-cyclohexenones as major products or α,β-cyclohexenones exclusively, under different reaction conditions.
一种阳离子 Rh(I)-催化的 [5 + 1] 环加成反应,使乙烯基环丙烷和 CO 反应,在不同的反应条件下,主要生成 β,γ-环己烯酮或 α,β-环己烯酮。