使用钳式 NHC/钯催化剂实现醇的交叉偶联反应，生成碳-碳键。
Cross-coupling reaction of alcohols for carbon-carbon bond formation using pincer-type NHC/palladium catalysts.
机构信息
Department of Chemistry, Graduate School of Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan.
出版信息
Org Biomol Chem. 2010 Feb 21;8(4):896-900. doi: 10.1039/b914618k. Epub 2009 Dec 17.
DOI:10.1039/b914618k
PMID:20135049
Abstract
A cross-coupling reaction of different alcohols was achieved using a pincer-type NHC/PdBr complex as the catalyst precursor, and the reaction, under either Ar or H(2) gas, displayed a broad substrate scope with respect to both primary and secondary alcohol components, with high alcohol product selectivity.
摘要
一种钳式 NHC/PdBr 配合物作为催化剂前体，实现了不同醇的交叉偶联反应，无论是在 Ar 或 H(2)气体下，该反应对伯醇和仲醇组分都具有广泛的底物范围，并具有较高的醇产物选择性。
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