钯催化吲哚与 K(4)[Fe(CN)(6)]的直接氰化反应。
Palladium-catalyzed direct cyanation of indoles with K(4)[Fe(CN)(6)].
机构信息
Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China.
出版信息
Org Lett. 2010 Mar 5;12(5):1052-5. doi: 10.1021/ol1000439.
PMID:20141185
Abstract
Direct cyanation of indole derivatives has been achieved with nontoxic K(4)[Fe(CN)(6)] as cyanating agent through Pd-catalyzed C-H bond activation.
摘要
通过钯催化的 C-H 键活化，使用无毒的 K(4)[Fe(CN)(6)]作为氰化剂，实现了吲哚衍生物的直接氰化。
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