Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599-3290, USA.
Org Lett. 2010 Mar 5;12(5):944-7. doi: 10.1021/ol9029353.
Organozinc, -magnesium, and -lithium nucleophiles initiate a Brook/Ireland-Claisen rearrangement sequence of allylic silyl glyoxylates resulting in the formation of gamma,delta-unsaturated alpha-silyloxy acids.
有机锌、-镁和-lithium 亲核试剂引发烯丙基硅基乙二醛酸酯的 Brook/Ireland-Claisen 重排序列,生成 γ,δ-不饱和 α-硅氧基酸。