金膜上自组装银纳米颗粒增强Me-ADOTA的荧光发射
Enhanced Fluorescence Emission of Me-ADOTA by Self-Assembled Silver Nanoparticles on a Gold Film.
作者信息
Sørensen Thomas J, Laursen Bo W, Luchowski Rafal, Shtoyko Tanya, Akopova Irina, Gryczynski Zygmunt, Gryczynski Ignacy
机构信息
Center for Commercialization of Fluorescence Technologies, University of North Texas Health Science Center, Fort Worth, TX 76107, USA.
出版信息
Chem Phys Lett. 2009 Jul 1;476(1):46-50. doi: 10.1016/j.cplett.2009.05.064.
Abstract
We report a multi-fold enhancement of the fluorescence of methyl-azadioxatriangulenium chloride (Me-ADOTA*Cl) in PVA deposited on a 50 nm thick gold mirror carrying an evaporation induced self-assembly of colloidal silver nanoparticles (Ag-SACs). The average measured increase in fluorescence emission of about 50-fold is accompanied by hot spots with a local enhancement in brigthness close to 200. The long lifetime of the dye allows for the first direct determination of the correlation between the enhancement of emission intensity and the decrease in fluorescence lifetime. The Ag-SACs surface preparation and observed enhancements are highly reproducible. We believe that these robust plasmonic surfaces will find use in sensing platforms for ultrasensitive detection.
摘要
我们报道了在沉积于50纳米厚金镜上的聚乙烯醇（PVA）中，甲基氮杂二氧杂三角烯氯化物（Me-ADOTA*Cl）的荧光增强了数倍，该金镜承载着通过蒸发诱导自组装形成的胶体银纳米颗粒（Ag-SACs）。平均测量到的荧光发射增强约50倍，同时存在热点，其亮度局部增强接近200倍。染料的长寿命使得首次能够直接确定发射强度增强与荧光寿命缩短之间的相关性。Ag-SACs的表面制备以及观察到的增强效果具有高度可重复性。我们相信，这些坚固的等离子体表面将在超灵敏检测的传感平台中得到应用。
相似文献
1
Enhanced Fluorescence Emission of Me-ADOTA by Self-Assembled Silver Nanoparticles on a Gold Film.金膜上自组装银纳米颗粒增强Me-ADOTA的荧光发射
Chem Phys Lett. 2009 Jul 1;476(1):46-50. doi: 10.1016/j.cplett.2009.05.064.
2
Preparation of plasmonic platforms of silver wires on gold mirrors and their application to surface enhanced fluorescence.金镜上银线等离子体平台的制备及其在表面增强荧光中的应用。
ACS Appl Mater Interfaces. 2014;6(21):18780-7. doi: 10.1021/am504431j. Epub 2014 Oct 22.
3
Sandwich type plasmonic platform for MEF using silver fractals.用于金属增强荧光的三明治型等离子体平台，采用银分形结构。
Nanoscale. 2015 Nov 14;7(42):17729-34. doi: 10.1039/c5nr05834a.
4
Fluorescent biosensor for the detection of hyaluronidase: intensity-based ratiometric sensing and fluorescence lifetime-based sensing using a long lifetime azadioxatriangulenium (ADOTA) fluorophore.用于检测透明质酸酶的荧光生物传感器：基于强度的比率传感和使用长寿命氮杂二氧杂三角烯鎓（ADOTA）荧光团的基于荧光寿命的传感。
Anal Bioanal Chem. 2016 May;408(14):3811-21. doi: 10.1007/s00216-016-9472-5. Epub 2016 Mar 18.
5
Steady State and Time Resolved Fluorescence Studies of Azadioxatriangulenium (ADOTA) Fluorophore in Silica and PVA Thin Films.二氧化硅和聚乙烯醇薄膜中氮杂二氧杂三蝶烯鎓（ADOTA）荧光团的稳态和时间分辨荧光研究
Dyes Pigm. 2015 Jun 1;117:16-23. doi: 10.1016/j.dyepig.2015.01.027.
6
Plasmonic platforms of self-assembled silver nanostructures in application to fluorescence.自组装银纳米结构在荧光应用中的等离子体平台。
J Nanophotonics. 2010 Sep 22;4. doi: 10.1117/1.3500463.
7
Single molecule immunoassay on plasmonic platforms.等离子体平台上的单分子免疫分析。
Curr Pharm Biotechnol. 2010 Jan;11(1):96-102. doi: 10.2174/138920110790725384.
8
Enhanced fluorescence of curcumin on plasmonic platforms.金纳米颗粒增强姜黄素的荧光效应。
Curr Pharm Biotechnol. 2010 Feb;11(2):223-8. doi: 10.2174/138920110790909623.
9
Metal-enhanced immunoassays.金属增强免疫测定法。
Methods Mol Biol. 2012;875:217-29. doi: 10.1007/978-1-61779-806-1_10.
10
Precision synthesis: designing hot spots over hot spots via selective gold deposition on silver octahedra edges.精准合成：通过选择性地在银八面体边缘沉积金，在热点上设计热点。
Small. 2014 Dec 10;10(23):4940-50. doi: 10.1002/smll.201401242. Epub 2014 Jul 22.
引用本文的文献
1
Towards homogenous multiwell plate based pH sensors using a responsive triangulenium dye and an ATTO-647 reference dye.迈向基于响应性三角烯染料和ATTO-647参比染料的均质多孔板pH传感器。
RSC Adv. 2025 Jan 16;15(2):1438-1446. doi: 10.1039/d4ra07949c. eCollection 2025 Jan 9.
2
Azadioxatriangulenium and Diazaoxatriangulenium: Quantum Yields and Fundamental Photophysical Properties.氮杂二氧杂三角烯鎓盐和二氮杂二氧杂三角烯鎓盐：量子产率和基本光物理性质。
ACS Omega. 2017 Jan 24;2(1):193-203. doi: 10.1021/acsomega.6b00211. eCollection 2017 Jan 31.
3
Design, synthesis, and time-gated cell imaging of carbon-bridged triangulenium dyes with long fluorescence lifetime and red emission.具有长荧光寿命和红色发射的碳桥连三角烯鎓染料的设计、合成及时间分辨细胞成像
Chem Sci. 2018 Feb 23;9(12):3122-3130. doi: 10.1039/c8sc00089a. eCollection 2018 Mar 28.
4
C-Functionalized Cationic Diazaoxatriangulenes: Late-Stage Synthesis and Tuning of Physicochemical Properties.C-官能化阳离子二氮杂氧杂三角烯：后期合成及理化性质调控
Chemistry. 2018 Jul 17;24(40):10186-10195. doi: 10.1002/chem.201801486. Epub 2018 Jun 25.
5
Azadioxatriangulenium: Synthesis and Photophysical Properties of Reactive Dyes for Bioconjugation.氮杂二氧杂三角烯鎓盐：用于生物共轭的活性染料的合成及光物理性质
European J Org Chem. 2015 Oct;2015(28):6351-6358. doi: 10.1002/ejoc.201500888.
6
Diazaoxatriangulenium: synthesis of reactive derivatives and conjugation to bovine serum albumin.重氮杂三蝶烯鎓盐：活性衍生物的合成及其与牛血清白蛋白的共轭反应
Org Biomol Chem. 2016 Jan 21;14(3):1091-101. doi: 10.1039/c5ob02293b. Epub 2015 Dec 3.
7
Sandwich type plasmonic platform for MEF using silver fractals.用于金属增强荧光的三明治型等离子体平台，采用银分形结构。
Nanoscale. 2015 Nov 14;7(42):17729-34. doi: 10.1039/c5nr05834a.
8
Preparation of plasmonic platforms of silver wires on gold mirrors and their application to surface enhanced fluorescence.金镜上银线等离子体平台的制备及其在表面增强荧光中的应用。
ACS Appl Mater Interfaces. 2014;6(21):18780-7. doi: 10.1021/am504431j. Epub 2014 Oct 22.
9
Large Fluorescence Enhancements of Fluorophore Ensembles with Multilayer Plasmonic Substrates: Comparison of Theory and Experimental Results.多层等离子体基底对荧光团集合体的大幅荧光增强：理论与实验结果比较
J Phys Chem C Nanomater Interfaces. 2012 Oct 11;116(40):21563-21571. doi: 10.1021/jp3072876.
10
Azadioxatriangulenium (ADOTA): A long fluorescence lifetime fluorophore for large biomolecule binding assay.氮杂二氧杂三角烯鎓（ADOTA）：一种用于大型生物分子结合测定的长荧光寿命荧光团。
Methods Appl Fluoresc. 2013;1(2):25001. doi: 10.1088/2050-6120/1/2/025001.
本文引用的文献
1
Enhanced Fluorescence from Fluorophores on Fractal Silver Surfaces.分形银表面上荧光团的增强荧光
J Phys Chem B. 2003;107(34):8829-8833. doi: 10.1021/jp022660r.
2
Tuning the fluorescence emission spectra of a single molecule with a variable optical subwavelength metal microcavity.利用可变光学亚波长金属微腔调控单分子的荧光发射光谱。
Phys Rev Lett. 2009 Feb 20;102(7):073002. doi: 10.1103/PhysRevLett.102.073002. Epub 2009 Feb 18.
3
Single nanowire on a film as an efficient SERS-active platform.薄膜上的单根纳米线作为高效的表面增强拉曼光谱活性平台。
J Am Chem Soc. 2009 Jan 21;131(2):758-62. doi: 10.1021/ja807455s.
4
Enhanced fluorescent immunoassays on silver fractal-like structures.基于银分形结构的增强型荧光免疫分析
Anal Chem. 2008 Mar 15;80(6):1962-6. doi: 10.1021/ac7019915. Epub 2008 Feb 21.
5
Fluorescence amplification by electrochemically deposited silver nanowires with fractal architecture.通过具有分形结构的电化学沉积银纳米线进行荧光放大。
J Am Chem Soc. 2007 Oct 10;129(40):12117-22. doi: 10.1021/ja071981j. Epub 2007 Sep 13.
6
Metal particle-enhanced fluorescent immunoassays on metal mirrors.金属镜上的金属颗粒增强荧光免疫分析
Anal Biochem. 2007 Apr 15;363(2):239-45. doi: 10.1016/j.ab.2007.01.030. Epub 2007 Jan 26.
7
One- and two-photon induced fluorescence of Pacific Blue-labeled human serum albumin deposited on different core size silver colloids.沉积在不同核心尺寸银胶体上的太平洋蓝标记人血清白蛋白的单光子和双光子诱导荧光。
Biopolymers. 2006 Mar;81(4):249-55. doi: 10.1002/bip.20407.
8
2,6,10-Tris(dialkylamino)trioxatriangulenium salts: a new promising fluorophore. Ion-pair formation and aggregation in non-polar solvents.2,6,10-三（二烷基氨基）三氧杂三角烯鎓盐：一种新的有前景的荧光团。在非极性溶剂中的离子对形成和聚集。
Photochem Photobiol Sci. 2005 Aug;4(8):568-76. doi: 10.1039/b501584g. Epub 2005 Jun 30.
9
Fluorescence enhancements on silver colloid coated surfaces.银胶体涂层表面的荧光增强。
J Fluoresc. 2004 Jul;14(4):417-23. doi: 10.1023/b:jofl.0000031823.04926.75.
10
Drying-mediated self-assembly of nanoparticles.纳米颗粒的干燥介导自组装
Nature. 2003 Nov 20;426(6964):271-4. doi: 10.1038/nature02087.
Zotero 插件