非活化脂肪族伯胺的 α-功能化：钌催化的炔基化和烷基化反应。
Alpha-functionalization of non-activated aliphatic amines: ruthenium-catalyzed alkynylations and alkylations.
机构信息
Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock, Germany.
出版信息
Chem Commun (Camb). 2010 Mar 21;46(11):1956-8. doi: 10.1039/b924674f. Epub 2010 Jan 14.
DOI:10.1039/b924674f
PMID:20198265
Abstract
Novel catalytic alpha-functionalizations of non-activated aliphatic amines with silylated alkynes are reported. In the presence of the Shvo catalyst alkylations and alkynylations proceed highly selectively to the branched amines.
摘要
报道了硅烷基炔烃对非活化脂肪族伯胺的新型催化α-官能化反应。在 Shvo 催化剂的存在下，烷基化和炔基化反应高度选择性地进行，得到支链伯胺。
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