用水相过氧化氢催化无金属条件下合成偕二氢过氧化物。
A facile catalyst-free synthesis of gem-dihydroperoxides with aqueous hydrogen peroxide.
机构信息
Gifu Pharmaceutical University, 5-6-1 Mitahora-higashi, Gifu 502-8585, Japan.
出版信息
Chem Commun (Camb). 2010 Mar 14;46(10):1772-4. doi: 10.1039/b917056a. Epub 2010 Jan 14.
DOI:10.1039/b917056a
PMID:20177645
Abstract
gem-Dihydroperoxides were easily obtained from the corresponding carbonyl compounds in high yields through a catalyst-free method with aqueous H(2)O(2) (35%) in 1,2-dimethoxyethane at room temperature.
摘要
通过在室温下，在 1,2-二甲氧基乙烷中用 35%的过氧化氢水溶液作为无催化剂方法，很容易从相应的羰基化合物中以高产率获得二氢过氧化物。
Zotero 插件