Chiu Chih-Wei, Lee Shih-Hao, Lin Ming-Fa
Department of Physics, National Cheng Kung University, Tainan 701, Taiwan.
J Nanosci Nanotechnol. 2010 Apr;10(4):2401-8. doi: 10.1166/jnn.2010.2160.
For doped armchair carbon nanotubes, the free electrons in the conduction bands would cause the intraband single-particle and collective excitations. Both kinds of excitations would be split into two modes because of two different Fermi-momentum states (kF'S). The excited carriers might be deexcited through such Coulomb excitations. Regarding the case where the transferred momentum L = 0, the two single-particle and the lower-frequency collective excitation modes could be the efficient deexcitation channels. In the lowest bands, the decay rates of the electron states exhibit weak Fermi energy (E(F)) dependence, but the decay rates of the hole states become greater with the increase of E(F) except for the right-side k(F). Concerning the states in the higher bands, the L not equal 0 excitations also take part in the deexcitation processes. Both the electron and hole states have the same decay rates except for the case where the carriers decay to the lowest states. The decay rates contrast sharply with those of undoped carbon nanotubes and two-dimensional intercalated graphenes. It is domenated by the Fermi energy, the geometric structure and the dimensionalities. The femtosecond time-resolved photoelectron, transmission and fluorescence spectroscopies could be used to verify the predicted results.
对于掺杂扶手椅型碳纳米管,导带中的自由电子会引发带内单粒子激发和集体激发。由于两种不同的费米动量状态(kF),这两种激发都会分裂为两种模式。受激载流子可能会通过这种库仑激发去激发。对于转移动量L = 0的情况,两种单粒子激发模式和低频集体激发模式可能是有效的去激发通道。在最低能带中,电子态的衰减率表现出对费米能量(E(F))的弱依赖性,但除了右侧的k(F)外,空穴态的衰减率会随着E(F)的增加而增大。对于较高能带中的态,L不等于0的激发也参与去激发过程。除了载流子衰减到最低态的情况外,电子态和空穴态具有相同的衰减率。这些衰减率与未掺杂碳纳米管和二维插层石墨烯的衰减率形成鲜明对比。它由费米能量、几何结构和维度决定。飞秒时间分辨光电子能谱、透射光谱和荧光光谱可用于验证预测结果。