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微波辅助碳热还原法合成竹节状3C-SiC纳米线

Synthesis of bamboo-like 3C-SiC nanowires by microwave assisted carbothermal reduction.

作者信息

Lu Mingxia, Li Ang, Wang Tianhui, Wang Dan, Qin Weiping

机构信息

State Key Laboratory on Integrated Optoelectronics, College of Electronic Science and Engineering, Zhuhai College, Jilin University, Changchun 130012, China.

出版信息

J Nanosci Nanotechnol. 2010 Mar;10(3):2135-8. doi: 10.1166/jnn.2010.2093.

Abstract

In this paper, bamboo-like 3C-SiC nanowires were synthesized in minutes without a metal catalyst by a simple, fast, and low-cost microwave method. The as-synthesized nanowires were studied by X-ray diffraction, scanning electron microscopy, Raman spectra, and transmission electron microscopy. The results showed that the bamboo-like nanowires have a stem of cubic 3C-SiC and nodes consisting of a high number of stacking faults, which are crystalline 3C-SiC with a diameter of 20-100 nm and a length around several microns. A possible mechanism for growing bamboo-like SiC nanowires in a microwave is also proposed.

摘要

本文采用一种简单、快速且低成本的微波方法,在无金属催化剂的情况下,于数分钟内合成了竹节状3C-SiC纳米线。通过X射线衍射、扫描电子显微镜、拉曼光谱和透射电子显微镜对合成的纳米线进行了研究。结果表明,竹节状纳米线具有立方3C-SiC的茎干和由大量堆垛层错组成的节点,这些节点是直径为20-100nm、长度约为几微米的结晶3C-SiC。还提出了一种在微波中生长竹节状SiC纳米线的可能机制。

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