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薄石墨烯薄膜的方阻值和透光率是否存在根本限制?

Are there fundamental limitations on the sheet resistance and transmittance of thin graphene films?

机构信息

School of Physics and CRANN, Trinity College Dublin, Dublin 2, Ireland.

出版信息

ACS Nano. 2010 May 25;4(5):2713-20. doi: 10.1021/nn100343f.

Abstract

From published transmittance and sheet resistance data, we have calculated a figure of merit for transparent, conducting graphene films; the DC to optical conductivity ratio, sigma(DC)/sigma(Op). For most reported results, this conductivity ratio clusters around the values sigma(DC)/sigma(Op) = 0.7, 4.5, and 11. We show that these represent fundamental limiting values for networks of graphene flakes, undoped graphene stacks, and graphite films, respectively. The limiting value for graphene flake networks is much too low for transparent-electrode applications. For graphite, a conductivity ratio of 11 gives R(s) = 377Omega/ for T = 90%, far short of the 10 Omega/ minimum requirement for transparent conductors in current driven applications. However, we suggest that substrate-induced doping can potentially increase the 2-dimensional DC conductivity enough to make graphene a viable transparent conductor. We show that four randomly stacked graphene layers can display T approximately 90% and 10 Omega/ if the product of carrier density and mobility reaches nmu = 1.3 x 10(17) V(-1) s(-1). Given achieved doping values and attainable mobilities, this is just possible, resulting in potential values of sigma(DC)/sigma(Op) of up to 330. This is high enough for any transparent conductor application.

摘要

从已发表的透过率和方阻数据中,我们计算了透明导电石墨烯薄膜的品质因数;直流到光导率的比值,σ(DC)/σ(Op)。对于大多数报道的结果,这个电导率比值集中在 σ(DC)/σ(Op)=0.7、4.5 和 11 左右。我们表明,这些分别代表了石墨烯薄片网络、未掺杂石墨烯堆叠和石墨薄膜的基本极限值。对于透明电极应用,石墨烯薄片网络的极限值太低了。对于石墨,电导率比值为 11 时,R(s)=377Ω,对于 T=90%,远低于当前电流驱动应用中透明导体 10Ω的最低要求。然而,我们认为基底诱导掺杂有可能增加二维直流电导率,从而使石墨烯成为一种可行的透明导体。我们表明,如果载流子密度和迁移率的乘积达到 nμ=1.3×10(17)V(-1)s(-1),则四层随机堆叠的石墨烯层可以显示出 T 约为 90%和 10Ω。考虑到已实现的掺杂值和可达到的迁移率,这是有可能的,从而导致 σ(DC)/σ(Op)的潜在值高达 330。这对于任何透明导体应用都足够高了。

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