Soil and Water Science Department, University of Florida, Gainesville, FL 32611, USA.
Sci Total Environ. 2010 Jun 1;408(13):2667-73. doi: 10.1016/j.scitotenv.2010.03.001. Epub 2010 Apr 10.
Triclocarban (TCC) is an active ingredient in antibacterial bar soaps, a common constituent of domestic wastewater, and the subject of recent criticism by consumer advocate groups and academic researchers alike. Activated sludge treatment readily removes TCC from the liquid waste stream and concentrates the antimicrobial in the solid fraction, which is often processed to produce biosolids intended for land application. Greater than half of the biosolids generated in the US are land-applied, resulting in a systematic release of biosolids-borne TCC into the terrestrial and, potentially, the aquatic environment. Multiple data gaps in the TCC literature (including basic physicochemical properties and biosolids concentrations) prevent an accurate, quantitative risk assessment of biosolids-borne TCC. We utilized the USEPA Office of Prevention, Pesticides, and Toxic Substances (OPPTS) harmonized test guidelines to measure TCC solubility and log K(ow) values as 0.045 mg L(-1) and 3.5, respectively. The measured physicochemical 2 properties differed from computer model predictions. The mean concentration of TCC in 23 biosolids representative of multiple sludge processing methods was 19+/-11 mg kg(-1).
三氯卡班(TCC)是抗菌皂条中的一种活性成分,是家庭废水中的常见成分,也是消费者权益保护组织和学术研究人员最近批评的对象。活性污泥处理可以很容易地从液体废水中去除 TCC,并将抗菌剂浓缩在固体部分,而固体部分通常经过处理,以生产用于土地应用的生物固体。美国产生的生物固体中,有一半以上用于土地应用,导致生物固体携带的 TCC 系统性地释放到陆地,并且可能释放到水生环境中。TCC 文献中的多个数据空白(包括基本物理化学性质和生物固体浓度)阻碍了对生物固体携带的 TCC 进行准确、定量的风险评估。我们利用美国环保署(USEPA)预防、农药和有毒物质办公室(OPPTS)协调的测试指南,分别测量了 TCC 的溶解度和 log K(ow)值,分别为 0.045mg/L 和 3.5。实测物理化学性质与计算机模型预测值不同。23 种代表多种污泥处理方法的生物固体中 TCC 的平均浓度为 19+/-11mg/kg。