铑催化的酰腙与双官能芳基硼试剂的环化反应。
Rhodium-catalyzed annulation of ynamides with bifunctional arylboron reagents.
机构信息
School of Chemistry, University of Edinburgh, The King's Buildings, West Mains Road, Edinburgh EH9 3JJ, UK.
出版信息
Org Lett. 2010 Jun 4;12(11):2554-7. doi: 10.1021/ol100769p.
PMID:20446723
Abstract
Annulation of ynamides with arylboronic acids or esters containing an electrophilic functional group at the ortho-position proceeds under the action of rhodium catalysis to generate 2-amidoindenols or 2-amidoindenes, usually with good regioselectivity.
摘要
邻位带有亲电官能团的芳基硼酸或硼酸酯与ynamides 的环化反应在铑催化作用下进行，通常具有很好的区域选择性，生成 2-酰胺茚醇或 2-酰胺茚满。
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