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Copper-catalyzed Ficini [2 + 2] cycloaddition of ynamides.铜催化的酰亚胺[2 + 2]环加成反应。
Org Lett. 2010 Sep 3;12(17):3780-3. doi: 10.1021/ol101418d.
2
Enantioselective Ficini reaction: ruthenium/PNNP-catalyzed [2+2] cycloaddition of ynamides with cyclic enones.对映选择性菲西尼反应：钌/PNNP催化的烯酰胺与环状烯酮的[2+2]环加成反应。
Angew Chem Int Ed Engl. 2011 Mar 21;50(13):3072-4. doi: 10.1002/anie.201007753. Epub 2011 Feb 25.
3
Regiospecific Ficini [2 + 2] cycloaddition of ynamides with cyclic isoimidium salts under catalyst-free conditions.在无催化剂条件下，炔酰胺与环状异亚胺盐的区域特异性菲西尼[2 + 2]环加成反应。
Org Lett. 2014 Aug 15;16(16):4316-9. doi: 10.1021/ol5020587. Epub 2014 Aug 7.
4
Brønsted acid catalyzed Ficini [2 + 2] cycloaddition of ynamides with enones.
Org Biomol Chem. 2024 May 29;22(21):4264-4268. doi: 10.1039/d4ob00470a.
5
Cu-catalyzed asymmetric 1,3-dipolar cycloaddition of azomethine ylides with beta-phenylsulfonyl enones. Ligand controlled diastereoselectivity reversal.铜催化的亚胺叶立德与β-苯磺酰基烯酮的不对称 1,3-偶极环加成。手性配体控制的非对映选择性反转。
J Org Chem. 2010 Jan 1;75(1):233-6. doi: 10.1021/jo902103z.
6
Introducing a new class of N-phosphoryl ynamides via Cu(I)-catalyzed amidations of alkynyl bromides.通过铜（I）催化的炔基溴代酰胺化反应，引入一类新型 N-膦酰基炔酰胺。
Org Lett. 2011 Sep 16;13(18):4862-5. doi: 10.1021/ol201947b. Epub 2011 Aug 17.
7
Preparation of functionalized indoles and azaindoles by the intramolecular copper-mediated carbomagnesiation of ynamides.通过酰胺基炔的分子内铜介导的碳镁化反应制备功能化吲哚和氮杂吲哚。
Angew Chem Int Ed Engl. 2013 Sep 16;52(38):10084-8. doi: 10.1002/anie.201304380. Epub 2013 Aug 9.
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A Silver(I)-Catalyzed Intramolecular Ficini's [2 + 2] Cycloaddition Employing Ynamides.一种使用烯酰胺的银（I）催化分子内菲西尼[2+2]环加成反应。
Tetrahedron Lett. 2015 Jun 3;56(23):3463-3467. doi: 10.1016/j.tetlet.2015.01.017.
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Efficient approach to 4-sulfonamidoquinolines via copper(I)-catalyzed cascade reaction of sulfonyl azides with alkynyl imines.通过铜（I）催化的磺酰叠氮与炔基亚胺的级联反应高效合成 4-磺胺喹啉。
Org Lett. 2013 Apr 5;15(7):1480-3. doi: 10.1021/ol400219n. Epub 2013 Mar 22.
10
An intramolecular [2 + 2] cycloaddition of ketenimines via palladium-catalyzed rearrangements of N-allyl-ynamides.通过钯催化的 N-烯丙基-炔酰胺重排实现酮亚胺的分子内[2 + 2]环加成。
Org Lett. 2012 Jun 15;14(12):3214-7. doi: 10.1021/ol3013233. Epub 2012 Jun 5.
引用本文的文献
1
Asymmetric synthesis with ynamides: unique reaction control, chemical diversity and applications.炔酰胺的不对称合成：独特的反应控制、化学多样性及应用。
Chem Soc Rev. 2020 Dec 7;49(23):8543-8583. doi: 10.1039/d0cs00769b. Epub 2020 Oct 19.
2
A Silver(I)-Catalyzed Intramolecular Ficini's [2 + 2] Cycloaddition Employing Ynamides.一种使用烯酰胺的银（I）催化分子内菲西尼[2+2]环加成反应。
Tetrahedron Lett. 2015 Jun 3;56(23):3463-3467. doi: 10.1016/j.tetlet.2015.01.017.
3
AlCl₃-Catalyzed Ring Expansion Cascades of Bicyclic Cyclobutenamides Involving Highly Strained Cis,Trans-Cycloheptadienone Intermediates.三氯化铝催化的双环环丁烯酰胺的扩环级联反应，涉及高张力的顺式、反式环庚二烯酮中间体。
J Am Chem Soc. 2015 Apr 29;137(16):5596-601. doi: 10.1021/jacs.5b02561. Epub 2015 Apr 20.
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Torquoselective ring opening of fused cyclobutenamides: evidence for a cis,trans-cyclooctadienone intermediate.稠合环丁烯酰胺的扭矩选择性开环：顺式，反式 - 环辛二烯酮中间体的证据。
J Am Chem Soc. 2014 Jul 16;136(28):9802-5. doi: 10.1021/ja502252t. Epub 2014 Jul 3.
5
Ynamides in ring forming transformations.酰胺在成环转化中的应用。
Acc Chem Res. 2014 Feb 18;47(2):560-78. doi: 10.1021/ar400193g. Epub 2013 Oct 28.
6
Batch and flow photochemical benzannulations based on the reaction of ynamides and diazo ketones. Application to the synthesis of polycyclic aromatic and heteroaromatic compounds.基于炔酰胺和重氮酮反应的批量和流动光化学苯并环化。在多环芳烃和杂环芳烃化合物合成中的应用。
J Org Chem. 2013 Nov 15;78(22):11450-69. doi: 10.1021/jo402010b. Epub 2013 Oct 28.
7
N-allyl-N-sulfonyl ynamides as synthetic precursors to amidines and vinylogous amidines. An unexpected N-to-C 1,3-sulfonyl shift in nitrile synthesis.N-烯丙基-N-磺酰基炔酰胺作为脒和亚胺甲酰胺的合成前体。腈合成中意想不到的 N 到 C 1,3-磺酰基迁移。
J Org Chem. 2011 Jun 17;76(12):5092-103. doi: 10.1021/jo200780x. Epub 2011 May 24.
本文引用的文献
1
[2+2] Cycloaddition of ketenes with ynamides. A general method for the synthesis of 3-aminocyclobutenone derivatives.烯酮与烯炔酰胺的[2+2]环加成反应。一种合成3-氨基环丁烯酮衍生物的通用方法。
Tetrahedron. 2006 Apr 17;62(16):3815-3822. doi: 10.1016/j.tet.2005.11.088.
2
A Stereoselective Intramolecular Cyclopropanation via a De Novo Class of Push-Pull Carbenes Derived from DMDO-Epoxidations of Chiral Ynamides.通过一类由手性烯酰胺的DMDO环氧化反应衍生的新型推拉卡宾实现的立体选择性分子内环丙烷化反应。
New J Chem. 2010 Jan 1;34(7):1309-1316. doi: 10.1039/c0nj00063a.
3
Access to 2,5-diamidopyrroles and 2,5-diamidofurans by au(i)-catalyzed double hydroamination or hydration of 1,3-diynes.通过金(i)催化的 1,3-二炔的双氢胺化或水合反应来获得 2,5-二氨基吡咯和 2,5-二氨基呋喃。
Org Lett. 2010 Jun 18;12(12):2758-61. doi: 10.1021/ol1008685.
4
Rhodium-catalyzed annulation of ynamides with bifunctional arylboron reagents.铑催化的酰腙与双官能芳基硼试剂的环化反应。
Org Lett. 2010 Jun 4;12(11):2554-7. doi: 10.1021/ol100769p.
5
Stereoselective additions of thiyl radicals to terminal ynamides.手性硫自由基对末端炔酰胺的立体选择性加成。
Org Lett. 2010 Jun 4;12(11):2650-2. doi: 10.1021/ol1008679.
6
Ynamides: a modern functional group for the new millennium.ynamides：新千年的现代官能团。
Chem Rev. 2010 Sep 8;110(9):5064-106. doi: 10.1021/cr100003s.
7
Cu-catalyzed oxidative amidation of propiolic acids under air via decarboxylative coupling.铜催化丙炔酸的氧化酰胺化反应在空气中通过脱羧偶联进行。
Org Lett. 2010 May 7;12(9):2000-3. doi: 10.1021/ol1004615.
8
Ynamides: versatile tools in organic synthesis.酰亚胺：有机合成中的多功能工具。
Angew Chem Int Ed Engl. 2010 Apr 6;49(16):2840-59. doi: 10.1002/anie.200905817.
9
A divergent mechanistic course of Pd(0)-catalyzed aza-Claisen rearrangement and aza-Rautenstrauch-type cyclization of N-allyl ynamides.钯（0）催化的 N-烯丙基炔酰胺的氮杂-Claisen 重排和氮杂-Rautenstrauch 型环化的分歧机制途径。
Org Lett. 2010 Apr 16;12(8):1840-3. doi: 10.1021/ol100446p.
10
Cu-catalyzed N-alkynylation of imidazoles, benzimidazoles, indazoles, and pyrazoles using PEG as solvent medium.铜催化的咪唑、苯并咪唑、吲唑和吡唑的 N-炔基化反应，使用 PEG 作为溶剂介质。
J Org Chem. 2010 Feb 5;75(3):980-3. doi: 10.1021/jo902466f.
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