石墨烯锚定 Co(3)O(4)纳米粒子作为锂离子电池的阳极,具有增强的可逆容量和循环性能。
Graphene anchored with co(3)o(4) nanoparticles as anode of lithium ion batteries with enhanced reversible capacity and cyclic performance.
机构信息
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016, People's Republic of China.
出版信息
ACS Nano. 2010 Jun 22;4(6):3187-94. doi: 10.1021/nn100740x.
We report a facile strategy to synthesize the nanocomposite of Co(3)O(4) nanoparticles anchored on conducting graphene as an advanced anode material for high-performance lithium-ion batteries. The Co(3)O(4) nanoparticles obtained are 10-30 nm in size and homogeneously anchor on graphene sheets as spacers to keep the neighboring sheets separated. This Co(3)O(4)/graphene nanocomposite displays superior Li-battery performance with large reversible capacity, excellent cyclic performance, and good rate capability, highlighting the importance of the anchoring of nanoparticles on graphene sheets for maximum utilization of electrochemically active Co(3)O(4) nanoparticles and graphene for energy storage applications in high-performance lithium-ion batteries.
我们报告了一种简便的策略,用于合成纳米复合材料,即将 Co(3)O(4)纳米颗粒锚定在导电石墨烯上,作为高性能锂离子电池的先进阳极材料。所得的 Co(3)O(4)纳米颗粒尺寸为 10-30nm,均匀地锚定在石墨烯片上作为间隔物,以保持相邻的片层分离。这种 Co(3)O(4)/石墨烯纳米复合材料表现出优异的锂离子电池性能,具有较大的可逆容量、优异的循环性能和良好的倍率性能,突出了纳米颗粒在石墨烯片上的锚定对于最大限度地利用电化学活性 Co(3)O(4)纳米颗粒和石墨烯在高性能锂离子电池中的储能应用的重要性。