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基于特异性三氢键识别的聚胸腺嘧啶稳定金纳米粒子的三聚氰胺的可见及光散射光谱检测

Visual and light scattering spectrometric detections of melamine with polythymine-stabilized gold nanoparticles through specific triple hydrogen-bonding recognition.

机构信息

Education Ministry Key Laboratory on Luminescence and Real-Time Analysis, College of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, PR China.

出版信息

Chem Commun (Camb). 2010 Jul 21;46(27):4893-5. doi: 10.1039/c0cc00886a. Epub 2010 Jun 11.

DOI:10.1039/c0cc00886a
PMID:20539899
Abstract

Melamine can be sensitively detected in aqueous medium through its selective interaction with polythymine (polyT(n)) modified gold nanoparticles (AuNPs) by forming triple H-bonds, which results in aggregation of the polyT(n)-stabilized AuNPs, displaying variations of localized plasmon resonance features such as colour change from red to purple and enhanced localized surface plasmon resonance light scattering (LSPR-LS) signals.

摘要

三聚氰胺可以通过与多胸腺嘧啶核苷(polyT(n))修饰的金纳米粒子(AuNPs)的选择性相互作用在水相中被灵敏地检测到,形成三重氢键,导致polyT(n)稳定的 AuNPs 聚集,显示局部等离子体共振特征的变化,如颜色从红色变为紫色,以及增强的局部表面等离子体共振光散射(LSPR-LS)信号。

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