钯（0）/金（I）氧化还原不相容性，由芳基金（I）配合物的钯催化同偶联反应揭示。
Pd(0)/Au(I) redox incompatibilities as revealed by Pd-catalyzed homo-coupling of arylgold(I)-complexes.
机构信息
Caudill Laboratories, Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, NC 27599-3290, USA.
出版信息
Chem Commun (Camb). 2011 May 14;47(18):5172-4. doi: 10.1039/c1cc11055a. Epub 2011 Mar 31.
Abstract
A Pd(II)-catalyzed homo-coupling of Au(I)-aryls is reported. The reaction is driven by a Pd(0)/Au(I) redox reaction that generates a gold mirror and Pd(II), and illustrates one of the challenges for developing dual catalytic Au-Pd systems.
摘要
报道了一种 Pd(II) 催化的 Au(I)-芳基的同偶联反应。该反应是由 Pd(0)/Au(I) 氧化还原反应驱动的，该反应生成金镜和 Pd(II)，并说明了开发双催化 Au-Pd 体系的挑战之一。
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