Kim Hyeyoung, Senthil Karuppanan, Yong Kijung
Nanoscale Res Lett. 2009 Apr 19;4(8):802-808. doi: 10.1007/s11671-009-9318-6.
A novel double-layer nanostructure of silicon carbide and tungsten oxide is synthesized by a two-step thermal evaporation process using NiO as the catalyst. First, SiC nanowires are grown on Si substrate and then high density W(18)O(49) nanorods are grown on these SiC nanowires to form a double-layer nanostructure. XRD and TEM analysis revealed that the synthesized nanostructures are well crystalline. The growth of W(18)O(49) nanorods on SiC nanowires is explained on the basis of vapor-solid (VS) mechanism. The reasonably better turn-on field (5.4 V/mum) measured from the field emission measurements suggest that the synthesized nanostructures could be used as potential field emitters.
采用两步热蒸发工艺,以NiO为催化剂,合成了一种新型的碳化硅和氧化钨双层纳米结构。首先,在硅衬底上生长碳化硅纳米线,然后在这些碳化硅纳米线上生长高密度的W(18)O(49)纳米棒,形成双层纳米结构。XRD和TEM分析表明,合成的纳米结构结晶良好。基于气-固(VS)机制解释了W(18)O(49)纳米棒在碳化硅纳米线上的生长过程。场发射测量得到的合理较好的开启场(5.4 V/μm)表明,合成的纳米结构可作为潜在的场发射体。