Department of Analytical Chemistry, Chemical Faculty, Gdańsk University of Technology, ul, Narutowicza 11/12, 80-233, Gdańsk, Poland.
Rev Environ Contam Toxicol. 2010;206:95-114. doi: 10.1007/978-1-4419-6260-7_5.
Since ancient times, ships have sunk during storms, either as a result of collisions with other vessels or running onto rocks. However, the ever-increasing importance of crude oil in the twentieth century and the corresponding growth in the world's tanker fleet have drawn attention to the negative implications of sea transport. Disasters involving tankers like the Torrey Canyon or the Amoco Cadiz have shown how dramatic the consequences of such an accident may be. The effects of oil spills at sea depend on numerous factors, such as the physicochemical parameters of the oil, the characteristics of the environment affected, and the physical, chemical, and biological processes occurring there, such as evaporation, dissolution, dispersion, emulsification, photo-oxidation, biodegradation, and sedimentation. The combination of these processes reduces the concentrations of hydrocarbons in sediments and water and alters the chemical composition of spilled oils. In every case, oil spills pose a danger to fauna and flora and cause damage to sea and shores ecosystems. Many of the petroleum-related chemicals that are spilled are toxic, otherwise carcinogenic or can be bioaccumulated in the tissues of marine organisms. Such chemicals may then be biomagnified up the marine food chain from phytoplankton to fish, then to seals and other carnivorous sea mammals. Moreover, oil products can be accumulated and immobilized in bottom deposits for long periods of time. Oil spills are particularly dangerous when they occur in small inland seas that have intense sea traffic, e.g., the Baltic Sea.
自古以来,船只在风暴中沉没,要么是与其他船只相撞,要么是触礁。然而,二十世纪原油的重要性不断增加,以及世界油轮船队的相应增长,引起了人们对海上运输负面影响的关注。像“Torrey Canyon”号或“Amoco Cadiz”号这样的油轮灾难表明,此类事故的后果可能是多么严重。海上溢油的影响取决于许多因素,例如油的物理化学参数、受影响环境的特征以及在那里发生的物理、化学和生物过程,如蒸发、溶解、分散、乳化、光氧化、生物降解和沉降。这些过程的结合降低了沉积物和水中碳氢化合物的浓度,并改变了溢油的化学组成。在任何情况下,溢油都会对动植物区系造成危害,并对海洋和海岸生态系统造成损害。许多溢油相关的化学物质是有毒的,或者致癌的,或者可以在海洋生物组织中生物累积。然后,这些化学物质可以通过从浮游植物到鱼类、海豹和其他肉食性海洋哺乳动物的海洋食物链进行生物放大。此外,石油产品可以在底沉积物中积累和固定很长时间。当它们发生在海上交通繁忙的小型内陆海,如波罗的海时,溢油尤其危险。