State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China. ruihu@fjirsm ac.cn
J Am Chem Soc. 2010 Sep 1;132(34):11904-5. doi: 10.1021/ja1055033.
Bis[3-(5-nitroimino-1,2,4-triazolate)]-based energetic salts were synthesized in a simple, straightforward manner. They exhibit low solubility in available solvents, high hydrolytic stability, excellent thermal stability, high density, positive heat of formation, low shock sensitivity, and excellent detonation properties. The physical and energetic properties of some salts are similar and even superior to those of RDX.
双[3-(5-硝基亚氨基-1,2,4-三唑基)]基含能盐以简单直接的方式合成。它们在可用溶剂中的溶解度低,水解稳定性高,热稳定性好,密度大,生成热为正值,撞击感度低,爆炸性能优良。一些盐的物理和能量性质与 RDX 相似,甚至优于 RDX。