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三唑并[1,5-a:1',5'-e][1,2,4]三嗪及其衍生物：高密度能材料。

Tris(triazolo)benzene and its derivatives: high-density energetic materials.

机构信息

Department of Chemistry, University of Idaho, Moscow, ID 83844-2343, USA.

出版信息

Angew Chem Int Ed Engl. 2012 Sep 24;51(39):9881-5. doi: 10.1002/anie.201205134. Epub 2012 Sep 3.

DOI:10.1002/anie.201205134
PMID:22945830
Abstract

High-performance explosives: Tris(triazolo)benzene was synthesized and converted to its trinitro and trichloro derivatives (see scheme; R=NO(2), Cl). The heats of formation of this "high-nitrogen" compounds were calculated and combined with experimentally determined densities to determine detonation pressures and velocities. They exhibit high density, good thermal stability, high heats of formation, and moderate to good detonation properties.

摘要

高性能炸药

三（三唑并）苯被合成，并转化为其三硝基和三氯衍生物（见方案；R=NO(2), Cl）。该“高氮”化合物的生成热被计算出来，并与实验测定的密度相结合，以确定爆轰压力和速度。它们表现出高密度、良好的热稳定性、高生成热和中等至良好的爆炸性能。

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