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聚偏二氟乙烯微结构的通用制造方法。

Versatile methods for the fabrication of polyvinylidene fluoride microstructures.

机构信息

Department of Biomedical Engineering, The Ohio State University, Columbus, OH 43210, USA.

出版信息

Biomed Microdevices. 2010 Dec;12(6):1009-17. doi: 10.1007/s10544-010-9455-9.

DOI:10.1007/s10544-010-9455-9
PMID:20700656
Abstract

Polyvinylidene fluoride (PVDF) microstructures are of interest for a number of BioMEMS applications both for their piezoelectric and biocompatible properties. In this work, simple soft lithography-based techniques were developed to fabricate PVDF microstructures with diverse geometries, including microarrays of pillars, lines, and wells. Four different microstructure configurations were created: freestanding, stamped discontinuous, stamped continuous and imprinted patterns. Features with lateral dimensions down to 1 μm were consistently reproduced on 2.5 cm diameter areas. Atomic force microscopy (AFM) measurements of poled PVDF microstructures confirmed a marked inverse piezoelectric behavior. The techniques presented here have a number of advantages over previously demonstrated PVDF micropatterning approaches.

摘要

聚偏二氟乙烯(PVDF)微结构因其压电和生物相容性而引起了许多生物微机电系统(BioMEMS)应用的关注。在这项工作中,开发了简单的基于软光刻的技术来制造具有不同几何形状的 PVDF 微结构,包括柱子、线条和井的微阵列。创建了四种不同的微结构配置:自由站立、冲压不连续、冲压连续和压印图案。在 2.5 厘米直径的区域上一致地复制了具有低至 1 μm 横向尺寸的特征。极化 PVDF 微结构的原子力显微镜(AFM)测量证实了显著的逆压电行为。与之前展示的 PVDF 微图案化方法相比,这里提出的技术具有许多优势。

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Versatile methods for the fabrication of polyvinylidene fluoride microstructures.聚偏二氟乙烯微结构的通用制造方法。
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引用本文的文献

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Piezoelectric Response in Hybrid Micropillar Arrays of Poly(Vinylidene Fluoride) and Reduced Graphene Oxide.聚偏氟乙烯与还原氧化石墨烯混合微柱阵列中的压电响应
Polymers (Basel). 2019 Jun 20;11(6):1065. doi: 10.3390/polym11061065.
2
Vertically aligned P(VDF-TrFE) core-shell structures on flexible pillar arrays.柔性柱阵列上垂直排列的聚(偏二氟乙烯-三氟乙烯)核壳结构
Sci Rep. 2015 Jun 4;5:10728. doi: 10.1038/srep10728.
3
Nanoscale fabrication of the ferroelectric polymer poly(vinylidene fluoride with trifluoroethylene) P(VDF-TrFE) 75:25 thin films by atomic force microscope nanolithography.
通过原子力显微镜纳米光刻技术对铁电聚合物聚(偏二氟乙烯与三氟乙烯)P(VDF-TrFE)75:25薄膜进行纳米尺度制备。
Scanning. 2012 Nov-Dec;34(6):404-9. doi: 10.1002/sca.21024. Epub 2012 May 2.