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用氯化锌活化孔石莼制备的活性炭从水溶液中去除铅。

Removal of lead from aqueous solution by activated carbon prepared from Enteromorpha prolifera by zinc chloride activation.

机构信息

Laboratory of Fiber Materials and Modern Textile, Qingdao University, 308 Ningxia Road, Qingdao 266071, China.

出版信息

J Hazard Mater. 2010 Nov 15;183(1-3):583-9. doi: 10.1016/j.jhazmat.2010.07.063. Epub 2010 Jul 21.

Abstract

Activated carbon was prepared from Enteromorpha prolifera (EP) by zinc chloride activation. The physico-chemical properties of EP-activated carbon (EPAC) were characterized by thermal stability, zeta potential and Boehm titration methods. The examination showed that EPAC has a porous structure with a high surface area of 1688 m(2)/g. Batch adsorption experiments were carried out to study the effect of various parameters such as initial pH, adsorbent dosage, contact time and temperature on Pb(II) ions adsorption properties by EPAC. The kinetic studies showed that the adsorption data followed a pseudo second-order kinetic model. The isotherm analysis indicated that the adsorption data can be represented by Freundlich isotherm model. Thermodynamic studies indicated that the adsorption reaction was a spontaneous and endothermic process.

摘要

用氯化锌活化孔石莼(EP)制备了活性炭。采用热稳定性、动电电位和Boehm 滴定法对 EP 活性炭(EPAC)的理化性质进行了表征。结果表明,EPAC 具有多孔结构,比表面积高达 1688 m(2)/g。进行了批量吸附实验,以研究初始 pH 值、吸附剂用量、接触时间和温度等各种参数对 EPAC 吸附 Pb(II)离子性能的影响。动力学研究表明,吸附数据符合准二级动力学模型。等温线分析表明,吸附数据可用 Freundlich 等温线模型来表示。热力学研究表明,吸附反应是一个自发和吸热的过程。

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