Saville D A
Department of Chemical Engineering, Princeton University, NJ 08544.
Electrophoresis. 1990 Nov;11(11):899-902. doi: 10.1002/elps.1150111103.
The influence of convection on the structure of an isotachophoretic boundary is investigated using an asymptotic method to simplify the conservation equations. To illustrate the methodology it is applied to a simple strong electrolyte system consisting of three ions and the relevant equations solved numerically. The technique, however, is of general applicability and can be useful in exploring the influence of various flow processes on analytical and preparative electrophoretic separation techniques in addition to isotachophoresis.
利用渐近方法简化守恒方程,研究了对流对等速电泳边界结构的影响。为了说明该方法,将其应用于一个由三种离子组成的简单强电解质体系,并对相关方程进行了数值求解。然而,该技术具有普遍适用性,除了等速电泳外,还可用于探索各种流动过程对分析和制备电泳分离技术的影响。