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电化学石英晶体微天平(EQCM)研究离子和溶剂插入高度多孔活性炭中。

Electrochemical quartz crystal microbalance (EQCM) studies of ions and solvents insertion into highly porous activated carbons.

机构信息

Department of Chemistry, Bar-Ilan University, Ramat-Gan 52900, Israel.

出版信息

J Am Chem Soc. 2010 Sep 29;132(38):13220-2. doi: 10.1021/ja104391g.

DOI:10.1021/ja104391g
PMID:20828121
Abstract

Electrochemical quartz crystal microbalance (EQCM) technique provides a direct assessment to the behavior of electroadsorbed ions and solvent molecules confined in micropores of activated carbon electrodes in contact with practically important aprotic electrolyte solutions. The estimated value of the solvation number equal to 3 is evident for a partial desolvation of Li(+) cations when adsorbed in carbon micropores.

摘要

电化学石英晶体微天平 (EQCM) 技术为实际重要的非质子电解质溶液中,在活性炭电极微孔中受限的电吸附离子和溶剂分子的行为提供了直接评估。当锂离子被吸附在碳微孔中时,估计的溶剂化数等于 3,表明锂离子部分去溶剂化。

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