重新探讨 palau'amine 生物合成的 Kinnel-Scheuer 假说。
Revisiting the Kinnel-Scheuer hypothesis for the biosynthesis of palau'amine.
机构信息
Department of Biochemistry, UT Southwestern Medical Center at Dallas, 5323 Harry Hines Boulevard, Dallas, TX 75390-9038, USA.
出版信息
Chem Commun (Camb). 2011 Jan 7;47(1):427-9. doi: 10.1039/c0cc02214d. Epub 2010 Sep 16.
Abstract
We propose herein an alternative biosynthetic pathway for palau'amine in order to resolve the stereochemical issue from the original Kinnel-Scheuer hypothesis. Furthermore, we use this revised hypothesis as a guide toward the laboratory synthesis of palau'amine.
摘要
我们在此提出了 palau'amine 的另一种生物合成途径，以解决 Kinnel-Scheuer 假说中原有的立体化学问题。此外，我们还利用这一修正假说指导 palau'amine 的实验室合成。
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