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A straightforward route to functionalized trans-Diels-Alder motifs.
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A Diels-Alder approach to the enantioselective construction of fluoromethylated stereogenic carbon centers.
Chem Commun (Camb). 2012 Jan 11;48(3):413-5. doi: 10.1039/c1cc15889a. Epub 2011 Nov 11.
3
Lewis acid template-catalyzed asymmetric diels-alder reaction.
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Lewis acid catalyzed inverse electron-demand Diels-Alder reaction of 1,2-diazines.
Org Lett. 2010 Sep 17;12(18):4062-5. doi: 10.1021/ol101701z.
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Lewis Acid/Rhodium-Catalyzed Formal [3 + 3]-Cycloaddition of Enoldiazoacetates with Donor-Acceptor Cyclopropanes.
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Domino inverse electron-demand Diels-Alder/cyclopropanation reaction of diazines catalyzed by a bidentate Lewis acid.
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A tin-free route to trans-diels-alder motifs by visible light photoredox catalysis.
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10
Intramolecular Diels-Alder reactions of cycloalkenones: translation of high endo selectivity to trans junctions.
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Photocatalyzed Epimerization of Quaternary Stereocenters.
J Am Chem Soc. 2025 Apr 2;147(13):11080-11088. doi: 10.1021/jacs.4c16769. Epub 2025 Mar 19.
2
Stereochemical editing logic powered by the epimerization of unactivated tertiary stereocenters.
Science. 2022 Oct 28;378(6618):383-390. doi: 10.1126/science.add6852. Epub 2022 Oct 27.
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Radical Cation Cycloadditions Using Cleavable Redox Auxiliaries.
Org Lett. 2017 Jan 20;19(2):368-371. doi: 10.1021/acs.orglett.6b03545. Epub 2016 Dec 29.
5
Synthesis of Angularly Substituted trans-Fused Decalins through a Metallacycle-Mediated Annulative Cross-Coupling Cascade.
Angew Chem Int Ed Engl. 2016 Oct 10;55(42):13099-13103. doi: 10.1002/anie.201606962.
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Stereospecific cis- and trans-ring fusions arising from common intermediates.
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7
Pattern recognition analysis in complex molecule synthesis and the preparation of iso-Diels-Alder motifs.
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8
Halocycloalkenones as Diels-Alder dienophiles. Applications to generating useful structural patterns.
J Org Chem. 2013 Jan 4;78(1):204-10. doi: 10.1021/jo302230m. Epub 2012 Nov 27.
9
Intramolecular Diels-Alder reactions of cycloalkenones: translation of high endo selectivity to trans junctions.
J Am Chem Soc. 2012 Sep 26;134(38):16080-4. doi: 10.1021/ja307708q. Epub 2012 Sep 18.

本文引用的文献

1
Diels-Alder routes to angularly halogenated cis-fused bicyclic ketones: Readily accessible cyclynone intermediates.
Tetrahedron Lett. 2010 Sep 1;51(35):4653-4654. doi: 10.1016/j.tetlet.2010.06.135.
2
A Diels-Alder Route to Angularly Functionalized Bicyclic Structures.
Tetrahedron. 2010 Aug 1;66(33):6391-6398. doi: 10.1016/j.tet.2010.04.094.
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Syntheses of Isomerically Pure Reference Octalins and Hydrindanes.
Tetrahedron Lett. 2009 Sep 30;50(39):5482-5484. doi: 10.1016/j.tetlet.2009.07.068.
5
The Diels--Alder reaction in total synthesis.
Angew Chem Int Ed Engl. 2002 May 17;41(10):1668-98. doi: 10.1002/1521-3773(20020517)41:10<1668::aid-anie1668>3.0.co;2-z.
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Computer-assisted design of complex organic syntheses.
Science. 1969 Oct 10;166(3902):178-92. doi: 10.1126/science.166.3902.178.
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Pattern recognition in retrosynthetic analysis: snapshots in total synthesis.
J Org Chem. 2007 Jun 8;72(12):4293-305. doi: 10.1021/jo070871s.

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