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Rapid Solid-State Photopolymerization of Cyclic Acetal-Containing Acrylates.含环状缩醛丙烯酸酯的快速固态光聚合反应
Macromolecules. 2009 Mar 13;42(7):2433-2437. doi: 10.1021/ma802406j.
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New dental composites containing multimethacrylate derivatives of bile acids: a comparative study with commercial monomers.新型含胆酸多甲基丙烯酸酯衍生物的牙科复合材料:与商业单体的对比研究。
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Thiol-click chemistry: a multifaceted toolbox for small molecule and polymer synthesis.巯基-点击化学:小分子和聚合物合成的多功能工具箱。
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Covalent Adaptable Networks (CANs): A Unique Paradigm in Crosslinked Polymers.共价适应性网络(CANs):交联聚合物中的一种独特范例。
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Thiol-ene click chemistry.硫醇-烯点击化学。
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Analysis of association constant for ground state dye-electron acceptor complex of photoinitiator systems and the association constant effect on the kinetics of visible-light-induced polymerizations.光引发剂体系基态染料-电子受体复合物的缔合常数分析及其缔合常数对可见光诱导聚合动力学的影响。
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Stress relaxation via addition-fragmentation chain transfer in a thiol-ene photopolymerization.硫醇-烯光聚合中通过加成-断裂链转移实现的应力松弛
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Reactivity of Monovinyl (Meth)Acrylates Containing Cyclic Carbonates.含环状碳酸酯的单乙烯基(甲基)丙烯酸酯的反应活性
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Relationships between conversion, temperature and optical properties during composite photopolymerization.复合光固化过程中聚合转化率、温度和光学性能之间的关系。
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Wear behavior of light-cured dental composites filled with porous glass-ceramic particles.多孔玻璃陶瓷颗粒填充光固化牙科复合材料的磨损行为。
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复合牙科修复材料的最新进展和发展。

Recent advances and developments in composite dental restorative materials.

机构信息

Dept of Chemical & Biological Engineering, University of Colorado, UCB 424, Boulder, CO 80309, USA.

出版信息

J Dent Res. 2011 Apr;90(4):402-16. doi: 10.1177/0022034510381263. Epub 2010 Oct 5.

DOI:10.1177/0022034510381263
PMID:20924063
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3144137/
Abstract

Composite dental restorations represent a unique class of biomaterials with severe restrictions on biocompatibility, curing behavior, esthetics, and ultimate material properties. These materials are presently limited by shrinkage and polymerization-induced shrinkage stress, limited toughness, the presence of unreacted monomer that remains following the polymerization, and several other factors. Fortunately, these materials have been the focus of a great deal of research in recent years with the goal of improving restoration performance by changing the initiation system, monomers, and fillers and their coupling agents, and by developing novel polymerization strategies. Here, we review the general characteristics of the polymerization reaction and recent approaches that have been taken to improve composite restorative performance.

摘要

复合牙科修复体是一类具有独特性能的生物材料,其生物相容性、固化行为、美观性和最终材料性能受到严重限制。这些材料目前受到收缩和聚合诱导收缩应力、有限的韧性、聚合后仍存在的未反应单体以及其他一些因素的限制。幸运的是,近年来这些材料一直是大量研究的焦点,目标是通过改变引发体系、单体和填料及其偶联剂,以及开发新的聚合策略来改善修复体的性能。在这里,我们回顾了聚合反应的一般特征和最近为改善复合修复体性能而采取的方法。