University of Potsdam, Institute of Chemistry, Laboratory of Sustainable Organic Synthesis, Karl-Liebknecht-Str. 24-25, 14476 Golm, Germany.
Chem Soc Rev. 2011 Mar;40(3):1404-45. doi: 10.1039/b924852h. Epub 2010 Oct 13.
Two decades have passed since the metathesis polymerisation of α,ω-dienes was successfully demonstrated by the group of Wagener and the term acyclic diene metathesis (ADMET) polymerisation was coined. Since then, the advances of metathesis chemistry have allowed to expand the scope of this versatile polymerisation reaction that nowadays finds applications in different fields, such as polymer, material, or medicinal chemistry. This critical review provides an insight into the historical aspects of ADMET and a detailed overview of the work done to date applying this versatile polymerisation reaction (221 references).
自 Wagener 小组成功展示α,ω-二烯的复分解聚合以来，已经过去了二十年，并且提出了非循环二烯复分解聚合（ADMET）的术语。从那时起，复分解化学的进步使得这种多功能聚合反应的范围得以扩大，如今它在聚合物、材料或药物化学等不同领域都有应用。这篇综述批判性地回顾了 ADMET 的历史发展，并详细概述了迄今为止应用这种多功能聚合反应所做的工作（221 篇参考文献）。
