Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto 615-8510, Japan.
Chem Commun (Camb). 2011 Jan 28;47(4):1100-5. doi: 10.1039/c0cc02566f. Epub 2010 Oct 18.
Reactions cleaving carbon-carbon bonds with the assistance of transition metals as the catalyst have provided various molecular transformations that are otherwise difficult to execute, opening a scenic avenue along organic synthesis. Construction of structural motifs like medium-sized carbocycles and chiral quaternary carbon centres have been set within an access of such paradoxical approaches in the past decade.
在过渡金属作为催化剂的协助下，裂解碳-碳键的反应提供了各种难以实现的分子转化，为有机合成开辟了一条广阔的道路。在过去的十年中，通过这种矛盾的方法，已经可以构建像中环碳架和手性季碳中心这样的结构基元。
