双功能茚满催化剂促进的手性杂环螺色满-硫代色满配合物的对映选择性合成。
Enantioselective heterocyclic synthesis of spiro chromanone-thiochroman complexes catalyzed by a bifunctional indane catalyst.
机构信息
Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543.
出版信息
Chem Commun (Camb). 2010 Dec 28;46(48):9232-4. doi: 10.1039/c0cc03489d. Epub 2010 Nov 4.
PMID:21052574
Abstract
Novel asymmetric domino reactions of benzylidenechroman-4-ones and 2-mercaptobenzaldehydes for efficient construction of spiro chromanone-thiochroman complexes were accomplished with high yields and excellent selectivities via a novel bifunctional indane catalyst.
摘要
新型不对称多米诺反应，利用新型双功能茚满催化剂，高效构建螺色满-硫代色满杂合体系，苯亚甲基色满-4-酮和 2-巯基苯甲醛反应以高产率和优异的选择性得到产物。
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