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钯催化脱羧铃木反应和基于铜的芳基羧酸的正交 O-芳基化反应。

Pd-catalysed decarboxylative Suzuki reactions and orthogonal Cu-based O-arylation of aromatic carboxylic acids.

机构信息

Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China.

出版信息

Chem Commun (Camb). 2011 Jan 14;47(2):677-9. doi: 10.1039/c0cc04104a. Epub 2010 Nov 24.

DOI:10.1039/c0cc04104a
PMID:21103597
Abstract

Pd-catalysed decarboxylative Suzuki reactions and orthogonal Cu-based O-arylation reactions of aromatic carboxylic acids are reported. The new reactions may provide alternative routes for the synthesis of some biaryls and aromatic carboxylic esters.

摘要

报道了钯催化的脱羧铃木反应和芳香羧酸的正交铜基 O-芳基化反应。这些新反应可能为一些联苯和芳香羧酸酯的合成提供了替代途径。

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