Zhu Xinhua, Liu Zhiguo, Ming Naiben
National Laboratory of Solid State Microstructures, Department of Physics, Nanjing University, Nanjing 210093, China.
J Nanosci Nanotechnol. 2010 Jul;10(7):4109-23. doi: 10.1166/jnn.2010.2942.
Perovskite oxide materials display a wide spectrum of functional properties, including switchable polarization, piezoelectricity, pyroelectricity, and non-linear dielectric behavior. These properties are indispensable for application in electronic devices such as non-volatile memories, sensors, microactuators, infrared detectors, microwave phase filters, and so on. Recent advances in science and technology of perovskite oxide materials have resulted in the feature sizes of perovskite oxides-based electronic devices entering into nanoscale dimensions. At nanoscale perovskite oxide materials exhibit a pronounced size effect manifesting itself in a significant deviation of the properties of low-dimensional structures from the bulk and film counterparts. In the last decade low-dimensional perovskite nanosized oxides have been received much attention because of their superior physical and chemical properties. Among them, perovskite oxide nanowires are especially attractive for nanoscience studies and nanotechnology applications. Compared to other low-dimensional perovskite oxide systems, perovskite oxide nanowires are not only used as the building blocks of future nanodevices, but also they offer fundamental scientific opportunities for investigating the intrinsic size effects of physical properties. In the recent years, much progress has been made both in synthesis and physical property testing of perovskite oxide nanowires, which have a profound impact on the nanoelectronics. In this work, an overview of the state of art in perovskite oxide nanowires is presented, which covers their synthesis, property, and structural characterization. In the first part, the recent literatures for fabricating perovskite oxide nanowires with promising features, are critically reviewed. The second part deals with the recent advances on the physical property testing of perovskite oxide nanowires. The third part summarizes the recent progress on microstructural characterizations of perovskite oxide nanowires, to improve their crystalline quality, morphology and uniformity. Finally, this review concludes with some perspectives and outlook on the future developments of perovskite oxide nanowires.
钙钛矿氧化物材料展现出广泛的功能特性,包括可切换极化、压电性、热电性和非线性介电行为。这些特性对于诸如非易失性存储器、传感器、微致动器、红外探测器、微波相位滤波器等电子设备的应用而言不可或缺。钙钛矿氧化物材料的科学技术最新进展已使基于钙钛矿氧化物的电子设备的特征尺寸进入纳米尺度。在纳米尺度下,钙钛矿氧化物材料呈现出显著的尺寸效应,表现为低维结构的性质与块状和薄膜对应物的性质存在显著偏差。在过去十年中,低维钙钛矿纳米尺寸氧化物因其优异的物理和化学性质而备受关注。其中,钙钛矿氧化物纳米线对于纳米科学研究和纳米技术应用尤其具有吸引力。与其他低维钙钛矿氧化物体系相比,钙钛矿氧化物纳米线不仅用作未来纳米器件的构建单元,而且还为研究物理性质的内在尺寸效应提供了基础科学机遇。近年来,钙钛矿氧化物纳米线的合成及物理性质测试均取得了很大进展,这对纳米电子学产生了深远影响。在这项工作中,对钙钛矿氧化物纳米线的现状进行了综述,涵盖了它们的合成、性质和结构表征。第一部分对制备具有良好特性的钙钛矿氧化物纳米线的近期文献进行了批判性综述。第二部分论述了钙钛矿氧化物纳米线物理性质测试的最新进展。第三部分总结了钙钛矿氧化物纳米线微观结构表征的近期进展,以改善其晶体质量、形态和均匀性。最后,本综述以对钙钛矿氧化物纳米线未来发展的一些观点和展望作为结语。