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一维钙钛矿锰氧化物纳米结构:合成、表征、输运性质及应用的最新进展

One-Dimensional Perovskite Manganite Oxide Nanostructures: Recent Developments in Synthesis, Characterization, Transport Properties, and Applications.

作者信息

Li Lei, Liang Lizhi, Wu Heng, Zhu Xinhua

机构信息

National Laboratory of Solid State Microstructures, School of Physics, Nanjing University, Nanjing, 210093, China.

State Key Laboratory of Materials-Oriented Chemical Engineering (MCE), Nanjing University of Technology, Nanjing, 210009, China.

出版信息

Nanoscale Res Lett. 2016 Dec;11(1):121. doi: 10.1186/s11671-016-1320-1. Epub 2016 Mar 1.

Abstract

One-dimensional nanostructures, including nanowires, nanorods, nanotubes, nanofibers, and nanobelts, have promising applications in mesoscopic physics and nanoscale devices. In contrast to other nanostructures, one-dimensional nanostructures can provide unique advantages in investigating the size and dimensionality dependence of the materials' physical properties, such as electrical, thermal, and mechanical performances, and in constructing nanoscale electronic and optoelectronic devices. Among the one-dimensional nanostructures, one-dimensional perovskite manganite nanostructures have been received much attention due to their unusual electron transport and magnetic properties, which are indispensable for the applications in microelectronic, magnetic, and spintronic devices. In the past two decades, much effort has been made to synthesize and characterize one-dimensional perovskite manganite nanostructures in the forms of nanorods, nanowires, nanotubes, and nanobelts. Various physical and chemical deposition techniques and growth mechanisms are explored and developed to control the morphology, identical shape, uniform size, crystalline structure, defects, and homogenous stoichiometry of the one-dimensional perovskite manganite nanostructures. This article provides a comprehensive review of the state-of-the-art research activities that focus on the rational synthesis, structural characterization, fundamental properties, and unique applications of one-dimensional perovskite manganite nanostructures in nanotechnology. It begins with the rational synthesis of one-dimensional perovskite manganite nanostructures and then summarizes their structural characterizations. Fundamental physical properties of one-dimensional perovskite manganite nanostructures are also highlighted, and a range of unique applications in information storages, field-effect transistors, and spintronic devices are discussed. Finally, we conclude this review with some perspectives/outlook and future researches in these fields.

摘要

一维纳米结构,包括纳米线、纳米棒、纳米管、纳米纤维和纳米带,在介观物理和纳米级器件中具有广阔的应用前景。与其他纳米结构相比,一维纳米结构在研究材料物理性质(如电学、热学和力学性能)的尺寸和维度依赖性以及构建纳米级电子和光电器件方面具有独特优势。在一维纳米结构中,一维钙钛矿锰氧化物纳米结构因其异常的电子输运和磁性而备受关注,这些特性对于微电子、磁性和自旋电子器件的应用不可或缺。在过去的二十年里,人们付出了很多努力来合成和表征纳米棒、纳米线、纳米管和纳米带形式的一维钙钛矿锰氧化物纳米结构。探索并开发了各种物理和化学沉积技术以及生长机制,以控制一维钙钛矿锰氧化物纳米结构的形态、相同形状、均匀尺寸、晶体结构、缺陷和均匀化学计量比。本文全面综述了聚焦于一维钙钛矿锰氧化物纳米结构在纳米技术中的合理合成、结构表征、基本性质和独特应用的前沿研究活动。文章首先介绍了一维钙钛矿锰氧化物纳米结构的合理合成,然后总结了它们的结构表征。还重点介绍了一维钙钛矿锰氧化物纳米结构的基本物理性质,并讨论了其在信息存储、场效应晶体管和自旋电子器件中的一系列独特应用。最后,我们以对这些领域的一些观点/展望和未来研究作为本综述的结语。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0f7d/4773315/b2ce8ca334f8/11671_2016_1320_Fig1_HTML.jpg

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