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零售葡萄干中伏马菌素 B(2)和 B(4)的出现。

Occurrence of fumonisins B(2) and B(4) in retail raisins.

机构信息

Center for Microbial Biotechnology, Department of Systems Biology, Technical University of Denmark, Søltofts Plads, Building 221, DK-2800 Kgs Lyngby, Denmark.

出版信息

J Agric Food Chem. 2011 Jan 26;59(2):772-6. doi: 10.1021/jf103855x. Epub 2010 Dec 20.

Abstract

Concerns that raisins may be contaminated by fumonisins stem from the persistent occurrence of Aspergillus niger spores on raisins and the recent discovery of fumonisin production by A. niger on grapes, which leads to the widespread occurrence of fumonisin B(2) in wine. This study presents an LC-MS/MS survey of fumonisins in retail raisins. In 10 of 21 brands collected in Denmark, Germany, and The Netherlands, fumonisins B(2) and B(4) were detected at levels up to 13 and 1.3 μg/kg, respectively. Only fumonisin B(2) has been detected in wine, so the presence of fumonisin B(4) in raisins suggests that the fumonisins are produced mainly during the drying process concomitant with the decreasing water activity. Analysis of multiple packages from one manufacturer showed a 3-fold package-to-package variation, suggesting that a few raisins per package are contaminated.

摘要

人们担心葡萄干可能受到伏马菌素的污染,这是因为黑曲霉孢子在葡萄干上持续存在,而最近又发现黑曲霉在葡萄上产生伏马菌素,导致葡萄酒中广泛存在伏马菌素 B(2)。本研究对丹麦、德国和荷兰收集的 21 个品牌的零售葡萄干中的伏马菌素进行了 LC-MS/MS 调查。在 10 个品牌中,检测到伏马菌素 B(2)和 B(4)的含量分别高达 13 和 1.3 μg/kg。葡萄酒中只检测到伏马菌素 B(2),因此,伏马菌素 B(4)在葡萄干中的存在表明,这些伏马菌素主要是在干燥过程中产生的,与水活度的降低有关。对一个制造商的多个包装进行分析显示,包装之间存在 3 倍的差异,这表明每个包装中都有少数葡萄干受到了污染。

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