碳水化合物辅助荧光开启的葡萄糖亚氨基蒽基共轭物作为牛奶和血清环境中 Hg(II)的传感器。
Carbohydrate assisted fluorescence turn-on gluco-imino-anthracenyl conjugate as a Hg(II) sensor in milk and blood serum milieu.
机构信息
Bioinorganic Laboratory, Department of Chemistry, Indian Institute of Technology Bombay, Mumbai, India.
出版信息
Chem Commun (Camb). 2011 Mar 7;47(9):2565-7. doi: 10.1039/c0cc04967k. Epub 2010 Dec 23.
A new anthracenyl-imino-glucosyl conjugate (L) selectively senses Hg(2+) by turn-on fluorescence with a 13 ± 1 fold enhancement by forming a 2 : 1 complex in pH 5 to 10 even in the presence of several biologically and ecologically relevant metal ions, with a 25 ± 2% fluorescence enhancement at the EPA limit of 2 ppb. L is equally sensitive towards Hg(2+) in the presence of albumin proteins and in blood serum and milk.
一种新型蒽基亚氨基-葡萄糖基缀合物（L）在 pH 5 到 10 范围内通过形成 2:1 络合物选择性地感应 Hg(2+)，荧光增强 13 ± 1 倍，即使存在多种生物和生态相关的金属离子，在 EPA 限值 2 ppb 下荧光增强 25 ± 2%。L 在白蛋白蛋白和血清及牛奶存在下对 Hg(2+)同样敏感。
Zotero 插件