（哌嗪 - 1 - 鎓 - κN）三（硫氰酸根合 - κN）锌（II）
(Piperazin-1-ium-κN)tris-(thio-cyanato-κN)zinc(II).
作者信息
He Xiang, Liu Hong-Jiang, Li Ming-Xing
机构信息
Department of Chemistry, College of Science, Shanghai University, Shanghai 200444, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 6;64(Pt 1):m122. doi: 10.1107/S1600536807065087.
Abstract
Hydro-thermal reaction of NaSCN, piperazine, Zn(II) and 2,6-naphthalenedicarboxylic acid in aqueous solutions gave rise to the title complex, [Zn(NCS)(3)(C(4)H(11)N(2))]. The Zn(II) atom is four-coordinate with distorted tetra-hedral geometry and lies in a mirror plane. N-H⋯S hydrogen bonds assemble the mol-ecules to form a three-dimensional framework.
摘要
硫氰酸钠、哌嗪、锌（II）和2,6 -萘二甲酸在水溶液中的水热反应生成了标题配合物[Zn(NCS)(3)(C(4)H(11)N(2))]。锌（II）原子呈四配位，具有扭曲的四面体几何构型，且位于一个镜面平面内。N - H⋯S氢键将分子组装形成三维框架。
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