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μ-氧代-双-{氯代[三-(2-吡啶甲基)胺]铬(III)} 双(六氟磷酸根)盐

μ-Oxido-bis-{chlorido[tris-(2-pyridylmeth-yl)amine]chromium(III)} bis(hexafluoridophosphate).

作者信息

Li Sheng, Wang Shou-Bin, Zhang Fu-Li, Tang Kun

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 6;64(Pt 1):m2. doi: 10.1107/S1600536807061296.

DOI:10.1107/S1600536807061296
PMID:21200546
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2914886/
Abstract

The title compound, Cr(2)Cl(2)O(C(18)H(18)N(4))(2)(2), is isostructural with the V(III) analogue. Each Cr(III) atom is chelated by the tetra-dentate tris-(2-pyridylmeth-yl)amine ligand via four N atoms, and further coordinated by one Cl atom and one bridging O atom, giving a slightly distorted octa-hedral coordination geometry. The dinuclear complex is centrosymmetric, with the bridging O atom lying on a centre of inversion.

摘要

标题化合物Cr₂Cl₂O(C₁₈H₁₈N₄)₂₂与钒(III)类似物同构。每个Cr(III)原子通过四个N原子被四齿三(2 - 吡啶甲基)胺配体螯合，并进一步由一个Cl原子和一个桥连O原子配位，形成略微扭曲的八面体配位几何构型。双核配合物是中心对称的，桥连O原子位于对称中心上。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3053/2914886/9c2fef5051e9/e-64-000m2-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3053/2914886/9c2fef5051e9/e-64-000m2-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3053/2914886/9c2fef5051e9/e-64-000m2-fig1.jpg

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引用本文的文献

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Retraction of articles.文章撤稿。
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本文引用的文献

1
Mononuclear oxovanadium complexes of tris(2-pyridylmethyl)amine.三（2-吡啶甲基）胺的单核氧钒配合物
Dalton Trans. 2005 Apr 21(8):1438-47. doi: 10.1039/b414532a. Epub 2005 Mar 11.