μ-氧代-双-{氯代[三-(2-吡啶甲基)胺]锰(III)} 双-(六氟磷酸根)
μ-Oxido-bis-{chlorido[tris-(2-pyridylmethyl)amine]manganese(III)} bis-(hexa-fluorido-phosphate).
作者信息
Meng Qingguo, Wang Lintong, Liu Yanzhen, Pang Yan
机构信息
College of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 18;64(Pt 1):m204. doi: 10.1107/S1600536807066512.
Abstract
In the title compound, Mn(2)O(C(18)H(18)ClN(4))(2)(2), the Mn atom is chelated by a tetra-dentate ligand via four N atoms, and further bonded to one chloride ion and one bridging oxide, to give a centrosymmetric cation and distorted octa-hedral coordination geometry.
摘要
在标题化合物Mn₂O(C₁₈H₁₈ClN₄)₂₂中，锰原子通过四个氮原子与一个四齿配体螯合，并进一步与一个氯离子和一个桥连氧原子键合，形成一个中心对称的阳离子和扭曲的八面体配位几何结构。
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