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μ-氧代-双-{氯代[三-(2-吡啶甲基)胺]锰(III)} 双-(六氟磷酸根)

μ-Oxido-bis-{chlorido[tris-(2-pyridylmethyl)amine]manganese(III)} bis-(hexa-fluorido-phosphate).

作者信息

Meng Qingguo, Wang Lintong, Liu Yanzhen, Pang Yan

机构信息

College of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 18;64(Pt 1):m204. doi: 10.1107/S1600536807066512.

DOI:10.1107/S1600536807066512
PMID:21200552
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2915134/
Abstract

In the title compound, Mn(2)O(C(18)H(18)ClN(4))(2)(2), the Mn atom is chelated by a tetra-dentate ligand via four N atoms, and further bonded to one chloride ion and one bridging oxide, to give a centrosymmetric cation and distorted octa-hedral coordination geometry.

摘要

在标题化合物Mn₂O(C₁₈H₁₈ClN₄)₂₂中，锰原子通过四个氮原子与一个四齿配体螯合，并进一步与一个氯离子和一个桥连氧原子键合，形成一个中心对称的阳离子和扭曲的八面体配位几何结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea53/2915134/b0916541ff44/e-64-0m204-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea53/2915134/b0916541ff44/e-64-0m204-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea53/2915134/b0916541ff44/e-64-0m204-fig1.jpg

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本文引用的文献

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An open-framework rare-earth acetylenedicarboxylate: MIL-95, Eu(III)2(H2O)2(CO3)2.{O2C-C2-CO2}.{H2O}x.
Inorg Chem. 2005 Feb 7;44(3):654-7. doi: 10.1021/ic0487373.
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Bis(mu-pyridine-2,6-carboxylato-O,N, O':O)bis[triaquamanganese(II)]-pyridine-2,6-dicarboxylic acid (1/2).双（μ-吡啶-2,6-羧酸根-O,N,O':O）双[三水合锰（II）]-吡啶-2,6-二羧酸（1/2）
Acta Crystallogr C. 2000 Dec;56(Pt 12):1416-7. doi: 10.1107/s0108270100012786.
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Three-dimensional structure of Escherichia coli dihydrodipicolinate reductase in complex with NADH and the inhibitor 2,6-pyridinedicarboxylate.大肠杆菌二氢二吡啶甲酸还原酶与NADH及抑制剂2,6-吡啶二甲酸复合物的三维结构。
Biochemistry. 1997 Dec 9;36(49):15081-8. doi: 10.1021/bi9719915.