Suppr超能文献

链状聚[[[二水合镉]-μ-2,2'-(1,2-苯二氧基)二乙酸根]一水合物]

catena-Poly[[[diaqua-cadmium]-μ-2,2'-(1,2-phenyl-enedi-oxy)diacetato] mono-hydrate].

作者信息

Hou Huan-Fu, Zhang Xiu-Ling

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Feb 16;67(Pt 3):m342. doi: 10.1107/S1600536811004867.

Abstract

In the title coordination complex, {[Cd(C(10)H(8)O(6))(H(2)O)(2)]·H(2)O}(n) the Cd(II) atom is seven-coordinated in a distorted penta-gonal-bipyramidal geometry, the penta-gonal plane comprising four O-atom donors from the 2,2'-(1,2-phenyl-enedi-oxy)diacetate chelate ligand together with a bridging carboxyl-ate O-atom donor, with the axial sites occupied by two water mol-ecules. The resulting helical chains extend along the b axis and are inter-connected by extensive O-H⋯O hydrogen-bonding inter-actions, which also involve the water mol-ecule of solvation, giving a three-dimensional structure.

摘要

在标题配位聚合物{[Cd(C₁₀H₈O₆)(H₂O)₂]·H₂O}ₙ中,Cd(II)原子以扭曲的五角双锥几何构型七配位,五角平面由来自2,2'-(1,2-苯二氧基)二乙酸螯合配体的四个O原子供体以及一个桥连羧酸根O原子供体组成,轴向位置由两个水分子占据。所得的螺旋链沿b轴延伸,并通过广泛的O—H⋯O氢键相互作用相互连接,这些相互作用还涉及溶剂化水分子,从而形成三维结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8132/3052000/c45b8a237f7c/e-67-0m342-fig1.jpg

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验